Nope. Try Qt or wxWidgets.
Win32 will certainly work, but it'll be alot of pain. Whatever you do, there'll be a learning curve, but IMO, Win32 is so low level that it's more of a learning wall than a curve.
Qt and wxWidgets are at a higher level of abstraction that makes it easier to get things up and running, while still retaining the same flexibility and power, with the added benefit of being cross-platform to Windows, Macintosh, and Linux.
Your mileage may vary.